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Journal of Thermoplastic Composite Materials
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Injection Molding and Properties of Highly Filled Copper-Polyamide 11 Composites

B. Beacgrlanger

B. Sanschagrin

B. Fisa

Centre de Recherche Appliqueacgre Sur Les Polymeres (CRASP), Eacgrcole Polytechnique de Montreacgral, Case Postale 6079, Succursale Centreville, Montreal (Queacgrbec), Canada H3C 3A 7

Copper-polyamide-I1 composites containing up to 90 wt.% of spherical copper powder were made using three approaches: (1) conventional injection molding of dry copper-polyamide powder blends, (2) compounding of powder blends and subsequent injection molding of composite pellets, and (3) direct molding of powder blends on an injection machine equipped with a vacuum hopper. The conventional molding of powders results in products having a significant porosity, which originates from the air dragged into the machine with the powder. The other two approaches can be used to produce essentially void-free materials. The mechanical properties are affected by the state of the filler surface. The "as-atomized" copper (which has a rough surface covered with an oxide layer) adheres better to the polymer than that whose surface was reduced to pure metal by hydrogen.

Key Words: copper • polyamide 11 • composite • injection molding

Journal of Thermoplastic Composite Materials, Vol. 10, No. 6, 532-542 (1997)
DOI: 10.1177/089270579701000603


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